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M. Haschke and T. H. Allen, J. , 2002, 336, 124. 49. L. Morales, T. Allen, and J. Haschke, AIP Conf. , 2000, 532, 114. 26. J. Wang, M. Kapon, J. C. Berthet, M. Ephritikhine, and M. S. Eisen, Inorg. Chim. Acta, 2002, 334, 183. 50. M. T. Paffett, D. Farr, and D. Kelly, AIP Conf. , 2003, 673, 193. 27. P. Scott and P. B. Hitchcock, Polyhedron, 1994, 13, 1651. 51. C. K. Rofer, D. A. Martinez, and V. L. Trujillo, NATO Sci. Ser. , 2000, 29, 131. 28. P. Scott and P. B. Hitchcock, J. Chem. : Inorg. , 1995, 603.

19 Redistribution reactions (see Redistribution Reaction), as we shall see below, are frequently encountered in the chemistry of Cp2 AnX2 compounds. A reaction scheme illustrating the utility of Cp3 UCl as a synthon in Cp3 UX chemistry is delineated in Scheme 1. 20 The molecular structures of a number of Cp3 AnX complexes have been determined, as well as the structures of related tris(indenyl)actinide halide compounds (see below). All possess a pseudotetrahedral geometry with the X ligand on an approximate threefold axis of symmetry.

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