Download Cobalt Oxides: From Crystal Chemistry to Physics by Prof. Dr. Bernard Raveau, Prof. Dr. Md. Motin Seikh(auth.) PDF

By Prof. Dr. Bernard Raveau, Prof. Dr. Md. Motin Seikh(auth.)

Extraordinary within the breadth and intensity of its assurance of all vital elements, this e-book systematically treats the digital and magnetic homes of stoichiometric and non-stoichiometric cobaltites in either ordered and disordered stages. Authored through a pioneer and a emerging superstar within the box, the monograph summarizes, organizes and streamlines the in a different way difficult-to-obtain details in this subject. An introductory bankruptcy units forth the crystal chemistry of cobalt oxides to put the basis for an knowing of the advanced phenomena saw during this fabrics type. exact emphasis is put on a accomplished dialogue of cobaltite actual homes in numerous structural households.

Providing an intensive creation to cobalt oxides from a chemical and actual perspective as a foundation for figuring out their intricacies, it is a must-have for either skilled researchers in addition to entrants to the field.

Content:
Chapter 1 Crystal Chemistry of Cobalt Oxides (pages 3–70):
Chapter 2 digital and Magnetic houses of Stoichiometric Perovskite Cobaltites (pages 71–128):
Chapter three digital and Magnetic homes of Oxygen?Deficient Perovskite Cobaltites Sr1?xLnxCoO3?? and SrCo1?xMxO3?? (pages 129–178):
Chapter four digital and Magnetic homes of Ruddlesden–Poepper?Type Cobaltites (pages 179–210):
Chapter five digital and Magnetic homes of Cobaltites with a 3D “Triangular Lattice” (pages 211–247):
Chapter 6 digital and Magnetic homes of “Triangular” Layered Cobaltites (pages 249–295):
Chapter 7 digital and Magnetic houses of the “Unidimensional” Cobaltite Ca3Co2o6 (pages 297–319):

Show description

By Prof. Dr. Bernard Raveau, Prof. Dr. Md. Motin Seikh(auth.)

Extraordinary within the breadth and intensity of its assurance of all vital elements, this e-book systematically treats the digital and magnetic homes of stoichiometric and non-stoichiometric cobaltites in either ordered and disordered stages. Authored through a pioneer and a emerging superstar within the box, the monograph summarizes, organizes and streamlines the in a different way difficult-to-obtain details in this subject. An introductory bankruptcy units forth the crystal chemistry of cobalt oxides to put the basis for an knowing of the advanced phenomena saw during this fabrics type. exact emphasis is put on a accomplished dialogue of cobaltite actual homes in numerous structural households.

Providing an intensive creation to cobalt oxides from a chemical and actual perspective as a foundation for figuring out their intricacies, it is a must-have for either skilled researchers in addition to entrants to the field.

Content:
Chapter 1 Crystal Chemistry of Cobalt Oxides (pages 3–70):
Chapter 2 digital and Magnetic houses of Stoichiometric Perovskite Cobaltites (pages 71–128):
Chapter three digital and Magnetic homes of Oxygen?Deficient Perovskite Cobaltites Sr1?xLnxCoO3?? and SrCo1?xMxO3?? (pages 129–178):
Chapter four digital and Magnetic homes of Ruddlesden–Poepper?Type Cobaltites (pages 179–210):
Chapter five digital and Magnetic homes of Cobaltites with a 3D “Triangular Lattice” (pages 211–247):
Chapter 6 digital and Magnetic homes of “Triangular” Layered Cobaltites (pages 249–295):
Chapter 7 digital and Magnetic houses of the “Unidimensional” Cobaltite Ca3Co2o6 (pages 297–319):

Show description

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Additional resources for Cobalt Oxides: From Crystal Chemistry to Physics

Sample text

5CoO3 matrix: it develops indeed large strains in the material that modify the crystallographic parameters, inducing atomic-scale lattice distortions. 8 (a) <100>pà HREM image showing the 90 -oriented domain texture of the nanoscale ordered LaBaCo2O6. (b) The Fourier transforms illustrate how the three orientation variants of 112-type domains can combine to form a 2D domain texture having {100}p planes as boundary planes. The domain size is typically in the range 5–10 nm. Adapted from Ref. [54].

9b). 80 [136]. 8 A. 10a). 10a). 10b) shows that the hexagonal windows formed by the trimetric units are obstructed by the single CoO6 octahedra (labeled B). 83 [138]. 60 [139]. 4 A. 11a) bordered by CoO4 tetrahedra. Between these layers Ba2þ cations are interleaved, which ensure the cohesion of the structure. 74: (a) perspective view of the structure along <110> showing the trimeric octahedral units of face-sharing octahedra running along ~ c (labeled A), interconnected through double layers of corner-sharing octahedra (labeled B).

214]. j39 40 j 1 Crystal Chemistry of Cobalt Oxides prism are shared with a CoO6 octahedron, but lower oxygen atoms are shared with three CoO6 octahedra. 70CoO2, there are two kinds of prisms, namely, Na(1) O6 and Na(2)O6 [216]. The Na(1)O6 prism shares two sets of three oxygen atoms with one upper and one lower CoO6 octahedra, respectively. On the other hand, the Na(2) O6 prism shares two sets of three oxygen atoms with upper and lower three CoO6 octahedra, respectively. From the above discussion, it is clear that the structure contains two different environments for sodium: Na(1) that lies between adjacent cobalt ions and Na(2) that sits on a lower energy site at the center of a cobalt trigonal prism.

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