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Extra resources for Comprehensive Coordination Chemistry II, Volume 1: Fundamentals: Ligands, Complexes, Synthesis, Purification, and Structure
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A great deal of license has been taken with the division between ‘‘coordination’’ and ‘‘organometallic’’ complexes; the formal distinction for the purposes of this series is that if more than 50% of the bonds are metal–carbon bonds then the compound is organometallic. , palladium(II) phosphine halides, to take a simple example) even when the important steps in the catalytic cycle involve formation and cleavage of M–C bonds. Likewise, many of the volatile molecules described in Chapter 23 as volatile precursors for MOCVD are organometallic metal alkyls; but they can be purified via formation of adducts with ligands such as bipyridine or diphosphines, and it would be artificial to exclude them and cover only ‘‘proper’’ coordination complexes such as diketonates and dithiocarbamates.