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M. Haschke and T. H. Allen, J. , 2002, 336, 124. 49. L. Morales, T. Allen, and J. Haschke, AIP Conf. , 2000, 532, 114. 26. J. Wang, M. Kapon, J. C. Berthet, M. Ephritikhine, and M. S. Eisen, Inorg. Chim. Acta, 2002, 334, 183. 50. M. T. Paffett, D. Farr, and D. Kelly, AIP Conf. , 2003, 673, 193. 27. P. Scott and P. B. Hitchcock, Polyhedron, 1994, 13, 1651. 51. C. K. Rofer, D. A. Martinez, and V. L. Trujillo, NATO Sci. Ser. , 2000, 29, 131. 28. P. Scott and P. B. Hitchcock, J. Chem. : Inorg. , 1995, 603.

19 Redistribution reactions (see Redistribution Reaction), as we shall see below, are frequently encountered in the chemistry of Cp2 AnX2 compounds. A reaction scheme illustrating the utility of Cp3 UCl as a synthon in Cp3 UX chemistry is delineated in Scheme 1. 20 The molecular structures of a number of Cp3 AnX complexes have been determined, as well as the structures of related tris(indenyl)actinide halide compounds (see below). All possess a pseudotetrahedral geometry with the X ligand on an approximate threefold axis of symmetry.

Organomet. , 2000, 604, 83. 25. J. Q. Wang, A. K. Dash, J. C. Berthet, M. Ephritikhine, and M. S. Eisen, Organometallics, 1999, 18, 2407. 39. B. P. Warner, J. A. D’Alessio, A. N. Morgan III, C. J. Burns, A. R. Schake, J. G. Watkin, Inorg. Chim. Acta 2000, 309, 45. 40. I. Castro-Rodriguez, K. Olsen, P. Gantzel, and K. Meyer, J. Am. Chem. , 2003, 125, 4565. 41. M. P. Wilkerson, C. J. Burns, H. J. Dewey, J. M. Martin, D. E. Morris, R. T. Paine, and B. L. Scott, Inorg. , 2000, 39, 5277. 42. D. E. Morris, M.

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