Download Heterogeneous Catalysis and Fine Chemicals III: Proceedings by M. Guisnet, J. Barbier, J. Barrault, D. Duprez, C. PDF

By M. Guisnet, J. Barbier, J. Barrault, D. Duprez, C. Montassier, G. Perot

Heterogeneous catalysis performs an important position within the natural synthesis of strong point and effective chemical substances. even if, because the interplay among floor websites and sensible teams is complicated, extra investigations are important into the results of catalysts at the response mechanisms. The 3rd foreign Symposium on Heterogeneous Catalysis and effective chemical substances supplied a chance for discussions at the easy and functional points of this topic among researchers, brands and clients of strong catalysts for synthesis of good chemical substances. This quantity includes the invited plenary lectures and study papers categorised less than the 3 major headings: hydrogenation, oxidation and acid-catalysis. All papers have been refereed. a wide number of reactions are defined, the emphasis being on selectivity, considering all facets: chemo-, regio- and stereoselectivity (including enantioselectivity) and at the switch of those selectivities as a functionality of the features of the catalysts and working stipulations.

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By M. Guisnet, J. Barbier, J. Barrault, D. Duprez, C. Montassier, G. Perot

Heterogeneous catalysis performs an important position within the natural synthesis of strong point and effective chemical substances. even if, because the interplay among floor websites and sensible teams is complicated, extra investigations are important into the results of catalysts at the response mechanisms. The 3rd foreign Symposium on Heterogeneous Catalysis and effective chemical substances supplied a chance for discussions at the easy and functional points of this topic among researchers, brands and clients of strong catalysts for synthesis of good chemical substances. This quantity includes the invited plenary lectures and study papers categorised less than the 3 major headings: hydrogenation, oxidation and acid-catalysis. All papers have been refereed. a wide number of reactions are defined, the emphasis being on selectivity, considering all facets: chemo-, regio- and stereoselectivity (including enantioselectivity) and at the switch of those selectivities as a functionality of the features of the catalysts and working stipulations.

Show description

Read Online or Download Heterogeneous Catalysis and Fine Chemicals III: Proceedings of the 3rd International Symposium, Poitiers, April 5-8, 1993 PDF

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Heterogeneous Catalysis and Fine Chemicals III: Proceedings of the 3rd International Symposium, Poitiers, April 5-8, 1993

Heterogeneous catalysis performs a big position within the natural synthesis of distinctiveness and nice chemical substances. although, because the interplay among floor websites and sensible teams is complicated, extra investigations are worthwhile into the consequences of catalysts at the response mechanisms. The 3rd foreign Symposium on Heterogeneous Catalysis and positive chemical compounds supplied a chance for discussions at the simple and useful points of this topic among researchers, brands and clients of sturdy catalysts for synthesis of good chemical substances.

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Extra resources for Heterogeneous Catalysis and Fine Chemicals III: Proceedings of the 3rd International Symposium, Poitiers, April 5-8, 1993

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Parshall, US. Patent 3 646 130 (1972). A. S. Patent 2 395 638 (1946). M. Roussel and H. Mimoun, J. , 45 (1980) 5387. J. Tsuji, H. Nagoshima and K. Hori, Chem. , 1980) 257. J. Buchler, S. Kruppa, M. Schmidt and G. Prescher, Eur. Patent 308 790 and 308 791 (1989). 24 G. Lagemaat, W. Drenth, M. Schmidt, G. Prescher and G. Goor, J. Mol. , 62 (1990) 119. 25 G. Goor, G . Prescher and M. Schmidt, in New Developments in Selective Oxidation (G. Centi and F. Trifirb, Eds), Studies in Surface Science and Catalysis, vol.

Other olefins, such as 1-hexen-3-01, give a mixture of threo and erythro isomers [59]. The oxidation of alcohol group, to yield the corresponding unsaturated ketones, preferentially occurs by decreasing the concentration of catalyst and hydrogen peroxide 26 and by increasing the pH [68-691. Vinyl acrylates are only epoxidized at the vinyl positions [65]. Under different reaction conditions, vicinal diol production [70] or C=C double bond oxidative cleavage to carboxylic acids occurs [59, 711. Dialdehydes are produced from cycloolefins, by tungstic acid as catalyst in t-butanol [72].

As with methyl pyruvate, a lower reaction temperature results in a higher optical yield albeit at a lower reaction rate. The influence of solvent is much more ronounced than with methyl pyruvate showing that modification in a solvent (C82CI ) which does not interact with the catalyst is of benefit. e of 5,200 is very fast, but gives a poor optical yield which is at odds with the methyl p ruvate reaction model. Ph [26]. At present there are very few reaction types catalysed by chiral modified supported catalysts.

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