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By C. Stumer; Alfred Hassner;

Because the book of "Organic Syntheses in response to identify Reactions and Unnamed Reactions"(Volume eleven within the Tetrahedron natural Chemistry series), there was a proliferation of discoveries of brand reactions within the box of natural chemistry. accordingly, this, the second one, revised, version of the textual content has all in favour of the continuing improvement during this region of study. The revised identify displays the proposal wherein many new reagents and reactions are actually being said by way of their names. The inclusion of over a hundred and fifty five new stereoselective and regioselective reagents or reactions together with uneven syntheses, brings the whole to over 540. gains that are meant to be precious to the reader comprise over 3000 references, a names index, reagent index, response index and a useful crew transformation index. The latter of those indexes will let the reader to look for conversions of 1 sensible team to a different and has proved a miles applied instrument for the substitute chemist, trying to find pathways to accomplish man made tactics.

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By C. Stumer; Alfred Hassner;

Because the book of "Organic Syntheses in response to identify Reactions and Unnamed Reactions"(Volume eleven within the Tetrahedron natural Chemistry series), there was a proliferation of discoveries of brand reactions within the box of natural chemistry. accordingly, this, the second one, revised, version of the textual content has all in favour of the continuing improvement during this region of study. The revised identify displays the proposal wherein many new reagents and reactions are actually being said by way of their names. The inclusion of over a hundred and fifty five new stereoselective and regioselective reagents or reactions together with uneven syntheses, brings the whole to over 540. gains that are meant to be precious to the reader comprise over 3000 references, a names index, reagent index, response index and a useful crew transformation index. The latter of those indexes will let the reader to look for conversions of 1 sensible team to a different and has proved a miles applied instrument for the substitute chemist, trying to find pathways to accomplish man made tactics.

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Additional resources for Organic Syntheses Based on Name Reactions - 2nd Edition (Tetrahedron Organic Chemistry)

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R. Aldrichimica Acta 1990 23 3 B A R T O N Deamination Free radical deamination of primary amines via isocyanides (see 1st edition). R. S. Chem. R. 2 mol equiv). 1 g) in xylene (50 mL) was slowly added at 80~ over 5 h. The solvent was removed in vacuum, the residue dissolved in pentane and iodine in pentane was added until the iodine color persisted. The solvent was evaporated and 4 was isolated by preparative TLC (silica gel, pentane). 205 g of 4 (81%), mp 29~ Organic Syntheses Based on Name Reactions 24 B A R T O N Phenylation of Phenols, Enols Phenylation of phenols, enols and other anions by a pentavalent organo-bismuth reagent under neutral, acidic or basic conditions.

Tetrahedron Lett. 1986 27 1715 4 Barluenga, J. J. Org. Chem. 1990 55 3104 5 Barluenga, J. Chem. 1993 58 2058 6 Barluenga, J. Ed. 1993 32 893 7 Goldfinger, M . B . Soc. 1994 116 7895 8 Baduenga, J. Am. Chem. Soc. 1997 119 6933 9 Barluenga, J. Tetrahedron Lett. 1998 39 7393 10 Barluenga, J. Angew. Chem. Int. Ed. 1998 37 3136 11 Barluenga, J. Pure Appl. Chem. 1999 71 431 12 Barluenga, J. Ed. 2001 40 3389 2623 Thiaanthracene 4. 36 mL, 54% in Et20, 10 mmol). 08 g, 10 mmol) in CH2CI2 was added and the reaction mixture was stirred.

Chem. 1981 46 873 7 Manitto, P. J. Org. Chem. 1995 60 484 B U R T O N Trifluoromethylation Trifluoromethylation of aryl iodides or nitroarenes with Cd(Cu) reagents (see 1st edition). I CF 3 CF3 F3CCdCI ! J. J. Am. Chem. Soc. J. J. Am. Chem. Soc. H. J. Chem. Soc. Chem. Commun. H. Tetrahedron Lett. 1989 638 30 2133 1-Trifluoromethyl-2,4-dinitrobenzene 2. 026 g of 2 (87%). 50 Organic Syntheses Based on Name Reactions B U C H W A L D Heterocyclization Preparation of benzisothiazoles, butenolides or pyrroles using organo-zirconium reagents and acetylenes.

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