By Gerard van Koten (auth.), Gerard van Koten, David Milstein (eds.)
Gerard van Koten: The Mono-anionic ECE-Pincer Ligand - a flexible Privileged Ligand Platform: basic Considerations.- Elena Poverenov, David Milstein: Non-Innocent habit of PCP and PCN Pincer Ligands of past due steel Complexes.- Dean M. Roddick: Tuning of PCP Pincer Ligand digital and Steric Properties.- Gemma R. Freeman, J. A. Gareth Williams: steel Complexes of Pincer Ligands: Excited States, Photochemistry, and Luminescence.- Davit Zargarian, Annie Castonguay, Denis M. Spasyuk: ECE-Type Pincer Complexes of Nickel.- Roman Jambor and Libor Dostál: The Chemistry of Pincer Complexes of thirteen - 15 major staff Elements.- Kálmán J. Szabo: Pincer Complexes as Catalysts in natural Chemistry.- Jun-ichi Ito and Hisao Nishiyama: Optically lively Bis(oxazolinyl)phenyl steel Complexes as Multi-potent Catalysts.- Anthony St. John, Karen I. Goldberg, and D. Michael Heinekey: Pincer Complexes as Catalysts for Amine Borane Dehydrogenation.- Dmitri Gelman and Ronit Romm: PC(sp3)P Transition steel Pincer Complexes: houses and Catalytic Applications.- Jennifer Hawk and Steve Craig: actual functions of Pincer Complexes.
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Extra resources for Organometallic Pincer Chemistry
1 Quinone Methides and Quinonoid Compounds . . . . . . . . . . . . . . . . . . . . 2 Phenoxonium Cation Complex . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Self-Oxidation of a Phenolate Complex to a Bimetallic Stilbene Quinone . . . . . 4 s-Coordinated Naphthyl Radical Anion . . . . . . . . . . . . . . . . . . . . . . . E. Poverenov • D. il 22 23 23 25 27 29 22 E. Poverenov and D.
Jonas K, Schieferstein L, Kruger C, Tsay YH (1979) Angew Chem Int Ed Engl 18:550 128. Bennett MA, Patmore JD (1971) Inorg Chem 10:2387 129. Muetterties EL, Hirsekorn FJ (1974) J Am Chem Soc 96:7920 130. Watson PL, Muetterties EL (1978) J Am Chem Soc 100:6978 131.
30 31 33 36 36 38 39 40 43 44 1 Introduction and Background Pincer-type complexes constitute a large family of important compounds in organometallic chemistry [1–5]. Such complexes play key roles in chemical transformations relevant to organic synthesis, catalysis, bond activation, mechanistic studies, and the design of new materials [6, 7]. By systematic ligand modifications and/or by variation of the metal center it has been possible to readily control their reactivity and stability.