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By Sutte C.A. (ed.)

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By Sutte C.A. (ed.)

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Extra info for Plant Growth Regulators. Chemical Activity, Plant Responses, and Econolllic Potential

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70 70 70 71 72 72 73 . . . 75 5 Applications to Asymmetric Ring Opening of Epoxides 6 Applications to Solid-Phase Synthesis . . . . . . . . 76 7 Perspectives . . . . . . . . . . . . . . . . 77 8 References . . . . . . . . . . . . . . . . 78 1 Introduction The chemistry of nucleophilic selenium reagents began in 1973 when Sharpless et al. reported a simple method to prepare a benzeneselenolate equivalent 1 and its usefulness in the nucleophilic ring opening of various epoxides [1].

58 58 59 60 61 62 63 63 64 66 67 68 Topics in Current Chemistry, Vol. 208 © Springer-Verlag Berlin Heidelberg 2000 56 4 M. Iwaoka · S. Tomoda . . . . . . . 1 Boron . . . . 2 Aluminum . . . 3 Indium . . . . 1 Silicon . . . . 2 Tin . . . . . . . . . . . . . . . . . . . . .

3 Reactions of Nucleophilic Selenium Species . . . . . . . 5 Reactions with Halides . . . . . . Ring Opening of Epoxides and Cyclic Ethers Reactions with Esters and Lactones . . . Michael Addition . . . . . . . . Miscellaneous . . . . . . . . . 2 . . . . . . . 57 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

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